My Windows 8.1 system can't accelerate with SSD to get Intel Smart Response Technology(SRT) working.

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Your GPT Mode O.S. HDD needs at least 5MB(Recommended 10MB) unallocated place for SRT to store the data. 
Please shrink a 5MB(Recommended 10MB) volume on your O.S. HDD and reboot to get SRT working.
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